Far‐Field Detection of Near‐Field Circular Dichroism Enhancements Induced by a Nanoantenna

Abstract

AbstractNanophotonics can enhance the inherent weak signal exhibited by chiral molecules in circular dichroism (CD) spectroscopy experiments. One mechanism to achieve this CD enhancement is based on increasing the optical chirality produced by nanophotonics antennas in their near‐field, where chiral molecules are placed. However, ascertaining whether this CD enhancement is reached presents significant experimental challenges due to the complexity of measuring near‐field optical chirality. Here, it is demonstrated that a local and single measurement of the degree of circular polarization in the far‐field enables quantifying near‐field CD enhancements. Thereby, based on this far‐field measurement, the optimal response of the antenna is predicted for enhanced chiral sensing. Experimental validation of this near‐to‐far‐field relation is provided for silicon spherical nanoantennas. The experimental results, supported by analytical theory and exact numerical simulations, can be interesting for the experimental characterization of devices capable of enhancing CD from a single far‐field Stokes measurement.