Effect of Ce Addition on Inclusions and Primary Carbide Network in AISI 440C Bearing Steel

Author:

Ma Shuai1,Li Yang1ORCID,Jiang Zhouhua1,Sun Meng1,Niedeng Yunfei1,Yang Rui1,Wang Yucheng1,Li Tianci1,Chen Changyong1,Liu Hang2

Affiliation:

1. School of Metallurgy Northeastern University NO. 3‐11, Wenhua Road, Heping District Shenyang 110819 P. R. China

2. Institute of Metal Research Chinese Academy of Sciences Shenyang 110016 P. R. China

Abstract

The effects of Ce on inclusions and the primary carbide network of AISI 440C bearing steel are experimentally and theoretically investigated. Adding Ce improves the cleanliness and refinement of primary carbide networks in AISI 440C bearing steel ingots. The addition of Ce substantially reduces the contents of total oxygen (T.O) and S in the steel, and MnS and Al2O3 inclusions are modified into finer Ce‐containing inclusions (Ce2O2S and Ce2O3). When Ce is added, the average equivalent diameter of the inclusions decreases from 1.82 to 1.33 μm, and the number of inclusions per unit area (mm2) increases from 59 to 105. Moreover, the addition of Ce reduces the secondary dendrite spacing from 33.82 to 24.2 μm, and the proportion of primary carbide is reduced from 22.08% to 11.17%. The 2D lattice disregistry theory confirms that Ce2O2S and Ce2O3 inclusions can be utilized as effective heterogeneous nucleation cores for γ‐Fe, thus refining the solidification microstructure and also the primary carbide. This study provides theoretical guidelines for the fabrication of domestic AISI 440C bearing steel ingots.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics

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