Hydrothermal Synthesis of Mixed Oxide Compositions of Cobalt‐Zirconium and their Catalytic Activity in the Decomposition of Hydrogen Peroxide

Author:

Ivanenko Oleksandr1ORCID,Pavlenko Tamara1,Pohorenko Yuliia1,Bykov Valeriy2

Affiliation:

1. Department of Electrochemistry and Technology of Inorganic Materials V.I. Vernadskyi Institute of General and Inorganic Chemistry of the Ukrainian NAS Palladina Ave, 32/34 03142 Kyiv Ukraine

2. Department of physical electronics Institute of Physics of the Ukrainian NAS Nauky Ave, 46 02000 Kyiv Ukraine

Abstract

AbstractThe article presents the results of research on the hydrothermal synthesis of nanoscale oxide of cobalt and zirconium and their mixed oxide compositions. The synthesized samples have been characterized by the X‐ray phase, scanning electron microscopy and nitrogen adsorption‐desorption methods; the composition of the samples has been determined by chemical analysis methods, and their catalytic activity in the decomposition of hydrogen peroxide has been studied. It has been shown that during synthesis, highly dispersed cobalt and zirconium oxide are formed, and the sample of the composition (mol %): Co3O4(88)−ZrO2(12) has the highest specific surface area (181.2 m2/g) and the highest activity (K=6.18 ⋅ 10−2 s−1) against the decomposition of hydrogen peroxide. The increasing of the ZrO2 content in oxide compositions reduces their catalytic activity. The particle size in the synthesized samples is 7–38 nm.

Publisher

Wiley

Subject

Inorganic Chemistry

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