Affiliation:
1. Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Northeast Normal University Changchun 130024 China
2. Shandong Peninsula Engineering Research Center of Comprehensive Brine Utilization Weifang University of Science and Technology Yantai, Shouguang 262700 China
3. Changchun Baoli Science and Technology Co Changchun 130024 China
Abstract
AbstractTo design and synthesize high‐nucleated titanium‐oxo clusters rationally based on molecular building blocks with potential coordination ability is still a great challenge. In this work, a family of titanium‐oxo clusters, including Ti2, Ti6, Ti12, and Ti20 clusters, have been assembled from large‐size ligand embonic acid‐modified {Ti2} molecular building blocks under solvothermal conditions. By modulating auxiliary linkers and solvent types, the {Ti2} building blocks exhibit varying degrees of polymerization to form high‐nuclear titanium‐oxo clusters. Notably, Ti20 with high nucleation, as the decamer containing {Ti2} building blocks, can act as a stable and heterogeneous catalyst to efficiently catalyze the oxidation of sulfides to sulfones and sulfoxides when using H2O2 as the green oxidant. This study provides a new approach for the design and synthesis of highly nucleated and homometallic TOCs based on {Ti2} units.
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1 articles.
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