Utility of a Ferrocene Unit in a Cyclometallated Cp*Ir(III) Catalyst during Water Oxidation: Exploring Bimetallic Cooperativity-Reference-Cited by-同舟云学术

Utility of a Ferrocene Unit in a Cyclometallated Cp*Ir(III) Catalyst during Water Oxidation: Exploring Bimetallic Cooperativity

Published:2023-08-10 Issue:28 Volume:26 Page:
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur J Inorg Chem

Author:

Gayen Firdaus Rahaman¹²^ORCID,Bora Debashree¹²^ORCID,Mallick Dibyendu³^ORCID,Sarbajna Abir⁴^ORCID,Ghosh Subrata²⁵,Jarugala Jayaramudu²⁶,Saha Biswajit¹²^ORCID

Affiliation:

1. Advanced Materials Group Materials Sciences and Technology Division CSIR-North East Institute of Science and Technology Jorhat Assam 785006 India

2. Academy of Scientific and Innovative Research (AcSIR) Ghaziabad 201002 India

3. Department of Chemistry Presidency University Kolkata 700073 India

4. Department of Chemistry School of Advanced Sciences Vellore Institute of Technology Vellore 632014 Tamil Nadu India

5. Natural Product Chemistry Group Chemical Sciences & Technology Division CSIR-North East Institute of Science and Technology Jorhat Assam 785006 India

6. Polymer and Petroleum Group Materials Sciences and Technology Division CSIR-North East Institute of Science and Technology Jorhat Assam 785006 India

Abstract

AbstractFerrocene functionalized 2‐phenylpyridine iridium(III) pentamethylcyclopentadienyl complex is synthesized and probed for oxygen evolution from water. The excellent activity of this system has been rationalized by proposing a Fe(III)/Ir(IV) transient intermediate where bimetallic redox synergism between the Fe and Ir centres possibly provide an alternative pathway rather than a conventional Ir(V) based cycle.

Funder

Science and Engineering Research Board

Publisher

Wiley

Subject

Inorganic Chemistry

Reference40 articles.

1. Solar Water Splitting Cells

2. Molecular Catalysts for Water Oxidation

3. Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation

4. Electrochemical Synthesis of Photoelectrodes and Catalysts for Use in Solar Water Splitting

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