In‐situ Etching Synthesis of Defective CuBTC for CO<sub>2</sub>/CH<sub>4</sub> Separation-Reference-Cited by-同舟云学术

In‐situ Etching Synthesis of Defective CuBTC for CO₂/CH₄ Separation

Published:2023-04-03 Issue:16 Volume:26 Page:
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur J Inorg Chem

Author:

Guo Biao¹,Xu Ruisong¹,Xu Ke¹,Liang Jing¹,Lu Jun¹,Wang Tonghua¹,Liu Jinxuan¹^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals Dalian University of Technology 116024 Dalian P. R. China

Abstract

AbstractWe report a facile in‐situ etching method for the synthesis of defective CuBTC (H‐CuBTC) with hierarchical pore structure. The fabricated mixed matrix membranes (MMMs) containing H‐CuBTC was prepared for the separation of CO2/CH4, showing superior separation performance due to the defective structure with larger pore size and more open Cu sites, which enhance the interactions between H‐CuBTC and the polymer.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.202200646

Reference39 articles.

1. A Chemically Functionalizable Nanoporous Material [Cu 3 (TMA) 2 (H 2 O) 3 ] n

2. Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage

3. In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth

4. Colloidal metal–organic framework particles: the pioneering case of ZIF-8

5. MOF-Based Membranes for Gas Separations

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Removing mesopores from metal-organic framework MIL-100(Cr) membranes for superior CO2 separation;Journal of Membrane Science;2024-06