Affiliation:
1. Universität Bielefeld, Fakultät für Chemie Centrum für Molekulare Materialien Universitätsstraße 25 33615 Bielefeld Germany
Abstract
AbstractTris(pentafluoroethyl)indane dihydrate, [In(C2F5)3(OH2)2], and the gallium analog, [Ga(C2F5)3(OH2)2], serve as transfer reagents for the In(C2F5)3 and Ga(C2F5)3 units, as illustrated by the preparation of salts of (pseudo)halogenotris(pentafluoroethyl)indate and ‐gallate anions, [M(C2F5)3)X]− (M=Ga, In; X=F, Cl, Br, I, CN, SCN). Due to the water tolerance and water solubility of [In(C2F5)3(OH2)2] and [Ga(C2F5)3(OH2)2], reactions can be performed in the presence of water or even in an aqueous medium.
Reference43 articles.
1.
2. H. Yamamoto K. Ishihara (Hrsg.)Acid catalysis in modern organic synthesis WILEY-VCH Weinheim 2008;
3. T. Thorwart L. Greb Encyclopedia of Inorganic and Bioinorganic Chemistry John Wiley & Sons Ltd 2021.
4. New Entries to Water-Compatible Lewis Acids
5. Lewis Superacids: Classifications, Candidates, and Applications
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献