Lewis Acid‐Assisted Molybdenum(VI) Complexes with <i>S</i>, <i>N</i>‐bidentate Ligands to Reduce Nitrate-Reference-Cited by-同舟云学术

Lewis Acid‐Assisted Molybdenum(VI) Complexes with S, N‐bidentate Ligands to Reduce Nitrate

Published:2023-01-18 Issue:9 Volume:26 Page:
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur J Inorg Chem

Author:

Lang Jia‐Jia¹,Mi Pengbing²,Wang Xiao‐Juan³,Gao Shu‐Qin³,Tan Xiangshi⁴,Lin Ying‐Wu¹³^ORCID

Affiliation:

1. Hengyang Medical College School of Chemistry and Chemical Engineering University of South China Hengyang 421001 P. R. China

2. Department of Pharmacy Hengyang Medicinal School University of South China Hengyang, Hunan 421001 P. R. China

3. Key Lab of Protein Structure and Function of Universities in Hunan Province University of South China Hengyang 421001 P. R. China

4. Department of Chemistry & Institute of Biomedical Science Fudan University Shanghai 200433 P. R. China

Abstract

AbstractTwo readily‐accessible molybdenum complexes with low sterically hindered S, N‐bidentate ligands were designed for the reduction of nitrate to nitrite. The Lewis acid Sc(III) acted as a significant co‐catalyst to enhance the catalytic efficiency by activating the N−O bond of nitrate. This study indicates that molybdenum complexes in cooperation with a Lewis acid offer functional Mo‐catalyst systems, which present functional artificial models of the natural molybdenum enzymes.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.202200727

Reference60 articles.

1. How Biology Handles Nitrite

3. Electrocatalytic reduction of nitrate – a step towards a sustainable nitrogen cycle

4. Reversing nitrogen fixation

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