Affiliation:
1. Graz University of Technology Institute of Inorganic Chemistry Stremayrgasse 9/IV 8010 Graz Austria
2. Graz University of Technology Institute for Chemistry and Technology of Materials Stremayrgasse 9/V 8010 Graz Austria
Abstract
AbstractInvestigation of the solubility behavior ofpara‐substituted (H, Me,t‐Bu,n‐Bu)meso‐tetraarylporphyrins as well asmeso‐tetraalkylporphyrins (Me,n‐Pr,n‐Bu) were performed. An increase of solubility in chloroform and benzene is detected according to the higher functionality inparaposition of the phenyl ring formeso‐tetraarylporphyrins or inmesoposition onmeso‐tetraalkylporphyrins. Furthermore, the series of bis(chlorido)tin(IV)meso‐tetraarylporphyrin and bis(chlorido)tin(IV)meso‐tetraalkylporphyrin was investigated via UV/Vis spectroscopy,119Sn‐NMR and single crystal X‐ray diffraction.
Funder
TU Graz, Internationale Beziehungen und Mobilitätsprogramme