Syntheses and Characterizations of Naphtho‐rhenafuran Complexes with S0 and T0 States

Author:

Zhan Liyan1,Wang Yarong2,Sun Caobo1,Tang Junping1,Zhao Yue1,Zhou Yan3,Li Yang2,Yu Limei1,Bai Wei1ORCID

Affiliation:

1. School of Chemistry Dalian University of Technology Dalian Liaoning 116024 P.R. China

2. School of Chemical Engineering Dalian University of Technology Dalian Liaoning 116024 P.R. China

3. School of Chemistry and Chemical Engineering Guangxi University for Nationalities Guangxi Key Laboratory of Chemistry and Engineering of Forest Products Key Laboratory of Guangxi Colleges Universities for Food Safety and Pharmaceutical Analytical Chemistry Nanning 530008 P.R. China

Abstract

AbstractReactions of o‐alkyl naphthol compounds with ReCl3(PMePh2)3 produced naphtho‐rhenafuran complexes, which adapted different ground states (singlet S0 and triplet T0). These polycyclic structures have been characterized experimentally and theoretically. Their electronic behaviors have been studied by UV‐Vis absorption and DFT calculations.

Funder

National Natural Science Foundation of China

Publisher

Wiley

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