A Family of Lanthanoid‐Sodium Multifunctional Coordination Polymers: Single‐Molecule Magnet, Luminescent and Magnetocaloric Properties

Author:

Troyano Alejandro Cuesta1ORCID,González Jonay1ORCID,Arauzo Ana2ORCID,Bartolomé Elena3ORCID,Sañudo E. Carolina14ORCID

Affiliation:

1. Secció de Química Inorgànica Departament de Química Inorgànica i Orgànica Facultat de Química Universitat de Barcelona C/Martí i Franqués 1–11 08028 Barcelona Spain

2. Instituto de Nanociencia y Materiales de Aragón (INMA) CSIC-Universidad de Zaragoza Departamento de Física de la Materia Condensada 50009 Zaragoza Spain

3. Institut de Ciència de Materials de Barcelona (ICMAB) CSIC Campus UAB 08193 Barcelona Spain

4. Institut de Nanociència i Nanotecnologia IN2UB. Universitat de Barcelona C/Martí i Franqués 1–11 08028 Barcelona Spain

Abstract

AbstractIn this paper we report the microwave assisted synthesis and characterization of a family of Na−Ln coordination polymers (CPs) of formula [NaDy2(MeCOO)2(SALOH)5(chpH)2] (1Ln, Ln=Eu, Gd, Tb, Dy, Ho, Y). The Na+ cations isolate Ln2 units in a one‐dimensional polymer. By changing the lanthanoid ions, we attain Single Molecule Magnet properties (1Dy), luminescent properties (1Eu, 1Tb, 1Ho), a diamagnetic material (1Y) and a material that presents magnetocaloric effect (1Gd).

Publisher

Wiley

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