2‐Pyridinyl/quinolyl‐phenylamino‐quinoline Complexes With CF3 and C2F5 Ligated Ni-Reference-Cited by-同舟云学术

2‐Pyridinyl/quinolyl‐phenylamino‐quinoline Complexes With CF3 and C2F5 Ligated Ni

Published:2024-08-21 Issue: Volume: Page:
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur J Inorg Chem

Author:

Håheim Katja S.¹,Deolka Shubham²,Fayzullin Robert R.³^ORCID,Lund Bjarte Aarmo⁴^ORCID,Khaskin Eugene²^ORCID,Sydnes Magne O.¹^ORCID

Affiliation:

1. Department of Chemistry Bioscience and Environmental Engineering University of Stavanger NO-4036 Stavanger Norway

2. Okinawa Institute of Science Technology Graduate University Tancha, Onna-son 904-0495 Okinawa Japan

3. Arbuzov Institute of Organic and Physical Chemistry FRC Kazan Scientific Center of RAS 8 Arbuzov Street Kazan 420088 Russian Federation

4. Department of Chemistry UiT The Arctic University of Norway NO-9037 Tromsø Norway

Abstract

AbstractA new ligand architecture based on quinoline/pyridine attached ortho to the amine functionality on an aniline, which is coupled to another quinoline unit has been prepared. Ligands L1 and L2 have been complexed with CF3 and C2F5 ligated nickel centers. The resulting complexes have been extensively studied by NMR spectroscopy (on 1H, 13C{1H}, and 19F nuclei) and single‐crystal X‐ray crystallography. A poorly defined mixture of complexes obtained from L1 and nickel bis‐trifluoromethyl complex was moderately active in C−H trifluoromethylation with the Umemoto I reagent.

Funder

Okinawa Institute of Science and Technology Graduate University

Publisher

Wiley

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