Complete Racemization in the Base Hydrolysis of Optically Active mer-[Chloro(diethylene triamine) (1,3-diaminopropan-2-ol-N,N?) cobalt (III)]tetrachlorozincate
Author:
Publisher
Wiley
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Drug Discovery,Biochemistry,Catalysis
Reference11 articles.
1. Octahedral substitution mechanisms and reactive intermediates
2. Stereochemical changes during octahedral substitution reactions
3. Competition studies and the stereochemistry for the base hydrolysis and induced aquation of some acidoamminebis(ethylenediamine)cobalt(III) ions
4. Acidopentaaminecobalt(III) complexes with polyamine ligands. X. The kinetics of aquation, base hydrolysis and racemisation of some chloro and aqua complexes containing six-membered chelate rings
5. unpublished results.
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1. Reactions ofmer(exo)- andmer(endo)-[Co(dien)(dapo)X]2+ Isomers (X=OH, Cl, ONO2, N3);Helvetica Chimica Acta;2003-01
2. Base Hydrolysis of Pentaaminecobalt (III) Complexes: The [CoX(dien) (dapo)]n+ system. Part 3. The internal conjugate base mechanism;Helvetica Chimica Acta;1992-06-24
3. Base Hydrolysis of Pentaaminecobalt(III) Complexes: The [CoX(dien) (dapo)]n+ system. Part 2. Structure and reactivity of the pentacoordinate intermediate;Helvetica Chimica Acta;1992-06-24
4. Base Hydrolysis of Pentaaminecobalt(III) Complexes: The [CoX(dien) (dapo)]n+ system. Part 1. Syntheses, structures, configuration, and spectroscopy;Helvetica Chimica Acta;1992-06-24
5. Anionopentaaminecobalt(III) complexes with polyamine ligands. 25. The resolution and base hydrolysis kinetics of mer-[CoCl(en)(NH2CH2CH NCH2CH2NH2)]ZnCl4, a complex with an unsymmetrical triamine ligand;Inorganica Chimica Acta;1986-05
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