Recent Advances in Understanding of the Singlet Oxygen in Energy Storage and Conversion

Abstract

AbstractSinglet oxygen (term symbol 1Δg, hereafter 1O2), a reactive oxygen species, has recently attracted increasing interest in the field of rechargeable batteries and electrocatalysis and photocatalysis. These sustainable energy conversion and storage technologies are of vital significance to replace fossil fuels and promote carbon neutrality and finally tackle the energy crisis and climate change. Herein, the recent progresses of 1O2 for energy storage and conversion is summarized, including physical and chemical properties, formation mechanisms, detection technologies, side reactions in rechargeable batteries and corresponding inhibition strategies, and applications in electrocatalysis and photocatalysis. The formation mechanisms and inhibition strategies of 1O2 in particular aprotic lithium‐oxygen (Li‐O2) batteries are highlighted, and the applications of 1O2 in photocatalysis and electrocatalysis is also emphasized. Moreover, the confronting challenges and promising directions of 1O2 in energy conversion and storage systems are discussed.