A Screening Approach to the Safe‐and‐Sustainable‐by‐Design Development of Advanced Insulation Materials

Author:

Di Battista Veronica12ORCID,Ribalta Carla3ORCID,Vilsmeier Klaus1,Singh Dilpreet4ORCID,Demokritou Philip5ORCID,Günther Eva6,Jensen Keld Alstrup3ORCID,Dekkers Susan7ORCID,Adam Veronique8,Wohlleben Wendel1ORCID

Affiliation:

1. Department of Analytical and Material Science and Department of Experimental Toxicology and Ecology BASF SE 67063 Ludwigshafen Germany

2. DTU Department of Environmental and Resource Engineering Kgs. Lyngby Denmark

3. National Research Centre for the Working Environment Lerso Parkallé 105 Copenhagen 2100 Denmark

4. Center for Nanotechnology and Nanotoxicology Harvard T.H. Chan School of Public Health Harvard University 665 Huntington Ave. Boston MA 02115 USA

5. Rutgers University Piscataway NJ 08854 USA

6. BASF Construction Additives GmbH Dr.‐Albert‐Frank‐Str. 32 83033 Trostberg Germany

7. TNO Unit Health Living & Work Risk Analysis for Products in Development Princetonlaan 6 Utrecht 3584 CB The Netherlands

8. TEMAS Solutions GmbH Lätterweg 5 Hausen 5212 Switzerland

Abstract

AbstractHerein, a Safe‐and‐Sustainable‐by‐Design (SSbD) screening strategy on four different inorganic aerogel mats and two conventional mineral wools for ranking purposes is demonstrated. Given that they do not consist of particles, the release is first simulated, addressing three occupational exposure scenarios, realistic for their intended use as building insulators. No exposure to consumers nor to the environment is foreseen in the use phase, however, aerosols may be released during mat installation, posing an inhalation risk for workers. All four aerogel mats release more respirable dust than the benchmark materials and 60% thereof deposits in the alveolar region according to modelling tools. The collected aerogel dust allows for subsequent screening of hazard implications via two abiotic assays: 1) surface reactivity in human blood serum; 2) biodissolution kinetics in lung simulant fluids. Both aerogels and conventional insulators show similar surface reactivity. Differences in biodissolution are influenced by the specifically designed organic and inorganic structural modifications. Aerogel mats are better‐performing insulators (2‐fold lower thermal conductivity than the benchmark) However, this work demonstrates how investment decisions can be balanced with safety and sustainability aspects. Concepts of analogy and similarity thus support easily accessible methods to companies for safe and economically viable innovation with advanced materials.

Funder

Horizon 2020

Publisher

Wiley

Reference76 articles.

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2. IndustryARC. Aerogel Market – Forecast(2023 –2028) https://www.industryarc.com/Report/15381/aerogels‐market.html (accessed: March 2024)

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