Affiliation:
1. Fujian Key Laboratory of Polymer Materials College of Chemistry and Materials Science Fujian Normal University Fuzhou 350007 China
2. State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 China
3. Advanced Research Institute of Multidisciplinary Science, and School of Chemistry and Chemical Engineering Beijing Institute of Technology Beijing 100081 China
Abstract
AbstractLi–CO2 batteries have attracted considerable attention for their advantages of CO2 fixation and high energy density. However, the sluggish dynamics of CO2 reduction/evolution reactions restrict the practical application of Li–CO2 batteries. Herein, a dual‐functional Mo2N–ZrO2 heterostructure engineering in conductive freestanding carbon nanofibers (Mo2N–ZrO2@NCNF) is reported. The integration of Mo2N–ZrO2 heterostructure in porous carbons provides the opportunity to simultaneously accelerate electron transport, boost CO2 conversion, and stabilize intermediate discharge product Li2C2O4. Benefiting from the synchronous advantages, the Mo2N–ZrO2@NCNF catalyst endows the Li–CO2 batteries with excellent cycle stability, good rate capability, and high energy efficiency even under high current densities. The designed cathodes exhibit an ultrahigh energy efficiency of 89.8% and a low charging voltage below 3.3 V with a potential gap of 0.32 V. Remarkably, stable operation over 400 cycles can be achieved even at high current densities of 50 µA cm−2. This work provides valuable guidance for developing multifunctional heterostructured catalysts to upgrade longevity and energy efficiency of Li–CO2 batteries.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Fujian Province
Natural Science Foundation of Beijing Municipality
State Key Laboratory of Structural Chemistry
Subject
Biomaterials,Biotechnology,General Materials Science,General Chemistry
Cited by
7 articles.
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