Niobium Oxide Anode with Lattice Structure Self‐Optimization for High‐Power and Nearly Zero‐Degeneration Battery Operation

Abstract

AbstractLi+ insertion‐induced structure transformation in crystalline electrodes vitally influence the energy density and cycle life of secondary lithium‐ion battery. However, the influence mechanism of structure transformation‐induced Li+ migration on the electrochemical performance of micro‐crystal materials is still unclear and the strategy to profit from such structure transformation remains exploited. Here, an interesting self‐optimization of structure evolution during electrochemical cycling in Nb2O5 micro‐crystal with rich domain boundaries is demonstrated, which greatly improves the charge transfer property and mechanical strength. The lattice rearrangement activates the Li+ diffusion kinetics and hinders the particle crack, thus enabling a nearly zero‐degeneration operation after 8000 cycles. Full cell paired with lithium cobalt oxides displays an exceptionally high capacity of 176 mA h g−1 at 8000 mA g−1 and excellent long‐term durability at 6000 mA g−1 with 63% capacity retention over 2000 cycles. Interestingly, a unique fingerprint based on the intensity ratio of two X‐ray diffraction peaks is successfully extracted as a measure of Nb2O5 electrochemical performance. The structure self‐optimization for fast charge transfer and high mechanical strength exemplifies a new battery electrode design concept and opens up a vast space of strategy to develop high‐performance lithium‐ion batteries with high energy density and ultra‐long cycle life.