The Collision between g‐C3N4 and QDs in the Fields of Energy and Environment: Synergistic Effects for Efficient Photocatalysis

Abstract

AbstractRecently, graphitic carbon nitride (g‐C3N4) has attracted increasing interest due to its visible light absorption, suitable energy band structure, and excellent stability. However, low specific surface area, finite visible light response range (<460 nm), and rapid photogenerated electron–hole (e−–h+) pairs recombination of the pristine g‐C3N4 limit its practical applications. The small size of quantum dots (QDs) endows the properties of abundant active sites, wide absorption spectrum, and adjustable bandgap, but inevitable aggregation. Studies have confirmed that the integration of g‐C3N4 and QDs not only overcomes these limitations of individual component, but also successfully inherits each advantage. Encouraged by these advantages, the synthetic strategies and the fundamental of QDs/g‐C3N4 composites are briefly elaborated in this review. Particularly, the synergistic effects of QDs/g‐C3N4 composites are analyzed comprehensively, including the enhancement of the photocatalytic performance and the avoidance of aggregation. Then, the photocatalytic applications of QDs/g‐C3N4 composites in the fields of environment and energy are described and further combined with DFT calculation to further reveal the reaction mechanisms. Moreover, the stability and reusability of QDs/g‐C3N4 composites are analyzed. Finally, the future development of these composites and the solution of existing problems are prospected.