Affiliation:
1. Collaborative Innovation Center of Metal Nanoclusters & Photo/Electro‐Catalysis and Sensing School of Materials Science and Engineering University of Jinan Jinan 250022 China
Abstract
AbstractIn this work, a series of Mo‐containing polyoxometalates (POMs) modified separators to inhibit the growth of lithium dendrites, and thus improving the lifespan and safety of the cells is proposed. When the deposited lithium forms dendrites and touches the separator, the optimized Dawson‐type POM of (NH4)6[P2Mo18O62]·11H2O (P2Mo18) with the stronger oxidizability, acts like a “killer”, is more inclined to oxidize Li0 into Li+, thus weakening the lethality of lithium dendrites. The above process is accompanied by the formation of Lix[P2Mo18O62] (x = 6–10) in its reduced state. Converting to the stripping process, the reduced state Lix[P2Mo18O62] (x = 6–10) can be reoxidized to P2Mo18, which achieves the reusability of P2Mo18 functional material. Meanwhile, lithium ions are released into the cell system to participate in the subsequent electrochemical cycles, thus the undesired lithium dendrites are converted into usable lithium ions to prevent the generation of “dead lithium”. As a result, the Li//Li symmetrical cell with P2Mo18 modified separator delivers exceptional cyclic stability for over 1000 h at 3 mA cm−2 and 5 mAh cm−2, and the assembled Li–S full cell maintains superior reversible capacity of 600 mAh g−1 after 200 cycles at 2 C.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Shandong Province
Subject
Biomaterials,Biotechnology,General Materials Science,General Chemistry
Cited by
1 articles.
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