Surface‐Reconstructed Ru‐Doped Nickel/Iron Oxyhydroxide Arrays for Efficient Oxygen Evolution

Abstract

AbstractThe generation of an active phase through dynamic surface reconstruction is a promising strategy for improving the activity of electrocatalysts. However, studies investigating the reconstruction process and its impact on the intrinsic properties of the catalysts are scarce. Herein, the surface reconstruction of NiFe2O4 interfaced with NiMoO4 (Ru–NFO/NMO) facilitated by Ru doping is reported. The electrochemical and material characterizations demonstrate that Ru doping can regulate the electronic structure of NFO/NMO and induce the high‐valence state of Ni3.6+δ, facilitating the surface reconstruction to highly active Ru‐doped NiFeOOH/NiOOH (SR‐Ru–NFO/NMO). The optimized SR‐Ru–NFO/NMO exhibits promising performance in the oxygen evolution reaction, displaying a low overpotential of 229 mV at 10 mA cm−2 and good stability at varying current densities for 80 h. Density functional theory calculations indicate that Ru doping can increase the electron density and optimize intermediate adsorption by shifting the d‐band center downward. This work provides valuable insights into the tuning of electrocatalysts by surface reconstruction and offers a rational design strategy for the development of highly active oxygen evolution reaction electrocatalysts.