Affiliation:
1. College of Materials Science and Engineering, Institute for Graphene Applied Technology Innovation Qingdao University Qingdao 266071 China
2. College of Materials Science and Engineering Linyi University Linyi Shandong 276000 China
Abstract
AbstractActive compounds based on LDH (ternary layered double hydroxide) are considered the perfect supercapacitor electrode materials on account of their superior electrochemical qualities and distinct structural characteristics, and flexible supercapacitors are an ideal option as an energy source for wearable electronics. However, the prevalent aggregation effect of LDH materials results in significantly compromised actual specific capacitance, which limits its broad practical applications. In this research, a 3D eggshell‐like interconnected porous carbon (IPC) framework with confinement and isolation capability is designed and synthesized by using glucose as the carbon source to disperse the LDH active material and enhance the conductivity of the composite material. Second, by constructing NiCoMn‐LDH nanocage structure based on ZIF‐67 (zeolitic imidazolate framework‐67) at the nanometer scale the obtained IPC/NiCoMn‐LDH electrode material can expose more active sites, which allows to achieve excellent specific capacitance (2236 F g−1/ 310.6 mAh g−1 at 1 A g−1), good rate as well as the desired cycle stability (85.9% of the initial capacitance upon 5000 cycles test). The constructed IPC/NiCoMn‐LDH//IPC ASC (asymmetric supercapacitor) exhibits superior capacitive property (135 F g−1/60.1 mAh g−1 at 0.5 A g−1) as well as desired energy density (40 Wh kg−1 at 800 W kg−1).
Subject
Biomaterials,Biotechnology,General Materials Science,General Chemistry
Cited by
1 articles.
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