Affiliation:
1. State Key Laboratory of Solidification Processing, Centre for Nano Energy Materials, School of Materials Science and Engineering Shaanxi Joint Laboratory of Graphene Northwestern Polytechnical University Xi'an 710072 P. R. China
2. Training Center for Engineering Practices Northwestern Polytechnical University Xi'an 710072 P. R. China
Abstract
AbstractHard carbons (HCs) are extensively investigated as the potential anodes for commercialization of sodium‐ion batteries (SIBs). However, the practical deployment of HC anode suffers from the retarded Na+ diffusion at the high‐rate or low‐temperature operation scenarios. Herein, a multiscale modification strategy by tuning HC microstructure on the particle level as well as replenishing extra Na+ reservoir for the electrode through a homogeneous presodiation therapy is presented. Consequently, the coulombic efficiency of HC anode can be precisely controlled till the close‐to‐unit value. Detailed kinetics analysis observes that the Na+ diffusivity can be drastically enhanced by two orders of magnitude at the low potential region (< 0.1 V vs. Na+/Na), which accelerates the rate‐limiting step. As pairing the presodiated HC anode (≈5.0 ± 0.2 mg cm−2) with the NaVPO4F cathode (≈10.3 mg cm−2) in the 200 mAh pouch cell, the optimal balance of the cyclability (83% over 1000 cycles), low‐temperature behavior till −40 °C as well as the maximized power output of 1500 W kg−1 can be simultaneously achieved. This synergistic modification strategy opens a new avenue to exploit the reversible, ultrafast Na+ storage kinetics of HC anodes, which thus constitutes a quantum leap forward toward high‐rate SIB prototyping.
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
Subject
Biomaterials,Biotechnology,General Materials Science,General Chemistry
Cited by
5 articles.
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