Recent Advances and Challenges in Efficient Selective Photocatalytic CO2 Methanation

Abstract

AbstractSolar‐driven carbon dioxide (CO2) methanation holds significant research value in the context of carbon emission reduction and energy crisis. However, this eight‐electron catalytic reaction presents substantial challenges in catalytic activity and selectivity. In this regard, researchers have conducted extensive exploration and achieved significant developments. This review provides an overview of the recent advances and challenges in efficient selective photocatalytic CO2 methanation. It begins by discussing the fundamental principles and challenges in detail, analyzing strategies for improving the efficiency of photocatalytic CO2 conversion to CH4 comprehensively. Subsequently, it outlines the recent applications and advanced characterization methods for photocatalytic CO2 methanation. Finally, this review highlights the prospects and opportunities in this area, aiming to inspire CO2 conversion into high‐value CH4 and shed light on the research of catalytic mechanisms.