MXene‐Bimetallic Hybrids via Mixed Molten Salts Etching for Kinetics‐Enhanced and Dendrite‐Free Lithium–Sulfur Batteries

Abstract

AbstractLithium–sulfur (Li–S) batteries with high theoretical energy density (2600 Wh kg−1) are considered to be one of the most promising secondary batteries. However, the practical application of Li–S batteries is limited by the polysulfides shuttling and unstable lithium metal anodes. Herein, an asymmetric separator (CACNM@PP), composed of Co–Ni/MXene (CNM) on the cathode and Cu–Ag/MXene (CAM) on the anode for high‐performance Li–S batteries is reported. For the cathode, CNM provides a synergistic effect by integrating Co, Ni, and MXene, resulting in strong chemical interactions and fast conversion kinetics for polysulfides. For the anode, CAM with abundant lithiophilicity active sites can lower the nucleation barrier of Li. Moreover, LiCl/LiF layers are generated in situ as an ion conductor layer during charging and discharging, inducing a uniform deposition of Li. Therefore, the assembled cells with the CACNM@PP separators harvest excellent electrochemical performance. This work provides novel insights into the development of commercially available high‐energy density Li–S batteries with asymmetric separators.