Affiliation:
1. College of Materials Science and Engineering Shenzhen University Shenzhen Guangdong 518055 P. R. China
2. School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou Guangdong 510006 P. R. China
3. Technological Institute of Materials & Energy Science (TIMES) Xi'an Key Laboratory of Advanced Photo‐electronics Materials and Energy Conversion Device School of Electronic Information Xijing University Xi'an Shaanxi 710123 P. R. China
Abstract
AbstractThe stability of aqueous Zn‐ion batteries (AZIBs) is detrimentally influenced by the formation of Zn dendrites and the occurrence of parasitic side reactions at the Zn metal anode (ZMA)‐electrolyte interface. The strategic manipulation of the preferential crystal orientation during Zn2+ plating serves as an essential approach to mitigate this issue. Here, Zn aspartate (Zn‐Asp), an electrolyte additive for AZIBs, is introduced not only to optimize the solvation structure of Zn2+, but also to crucially promote preferential Zn2+ plating on the (002) crystal plane of ZMA. As a result, both side reactions and Zn dendrites are effectively inhibited, ensuring an anode surface free of both dendrites and by‐products. The implementation of Zn‐Asp leads to significant enhancements in both Zn||Zn symmetric and Zn||Ti batteries, which demonstrate robust cyclability of over 3200 h and high Coulombic efficiency of 99.29%, respectively. Additionally, the Zn||NaV3O8·1.5H2O full battery exhibits remarkable rate capability, realizing a high capacity of 240.77 mA h g−1 at 5 A g−1, and retains 92.7% of its initial capacity after 1000 cycles. This research underscores the vital role of electrolyte additives in regulating the preferential crystal orientation of ZMA, thereby contributing to the development of high‐performing AZIBs.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Guangdong Province
Subject
Biomaterials,Biotechnology,General Materials Science,General Chemistry