Affiliation:
1. School of Physics and Electronic Engineering Sichuan University of Science & Engineering Yibin 644000 P. R. China
2. Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application School of Physical Science and Technology Suzhou University of Science and Technology Suzhou 215009 P. R. China
3. Department of Chemistry College of Sciences Nanjing Agricultural University Nanjing 210095 P. R. China
4. Department of Materials Science and Engineering and Center of Super‐Diamond and Advanced Films (COSDAF) City University of Hong Kong Hong Kong SAR 999077 P. R. China
Abstract
AbstractPristine iron triad metal–organic frameworks (MOFs), i.e., Fe‐MOFs, Co‐MOFs, Ni‐MOFs, and heterometallic iron triad MOFs, are utilized as versatile and promising cathodes for alkali metal‐ion batteries, owing to their distinctive structure characteristics, including modifiable and designable composition, multi‐electron redox‐active sites, exceptional porosity, and stable construction facilitating rapid ion diffusion. Notably, pristine iron triad MOFs cathodes have recently achieved significant milestones in electrochemical energy storage due to their exceptional electrochemical properties. Here, the recent advances in pristine iron triad MOFs cathodes for alkali metal‐ion batteries are summarized. The redox reaction mechanisms and essential strategies to boost the electrochemical behaviors in associated electrochemical energy storage devices are also explored. Furthermore, insights into the future prospects related to pristine iron triad MOFs cathodes for lithium‐ion, sodium‐ion, and potassium‐ion batteries are also delivered.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Jiangsu Province
City University of Hong Kong
Subject
Biomaterials,Biotechnology,General Materials Science,General Chemistry