Ultraviolet Circularly Polarized Luminescence in Chiral Perovskite Nanoplatelet‐Molecular Hybrids: Direct Binding Versus Efficient Triplet Energy Transfer

Author:

Tang Bing1,Wei Qi2,Wang Shixun1,Liu Haochen1,Mou Nanli1,Liu Qi1,Wu Ye1,Portniagin Arsenii S.1,Kershaw Stephen V.1,Gao Xiaoqing3,Li Mingjie2,Rogach Andrey L.1ORCID

Affiliation:

1. Department of Materials Science and Engineering, and Centre for Functional Photonics (CFP) City University of Hong Kong 83 Tat Chee Avenue Hong Kong SAR 999077 P. R. China

2. Department of Applied Physics The Hong Kong Polytechnic University Hung Hom Kowloon Hong Kong SAR 999077 P. R. China

3. Wenzhou Key Laboratory of Biophysics Wenzhou Institute University of Chinese Academy of Sciences Wenzhou 325000 P. R. China

Abstract

AbstractThe development of ultraviolet circularly polarized light (UVCPL) sources has the potential to benefit plenty of practical applications but remains a challenge due to limitations in available material systems and a limited understanding of the excited state chirality transfer. Herein, by constructing hybrid structures of the chiral perovskite CsPbBr3 nanoplatelets and organic molecules, excited state chirality transfer is achieved, either via direct binding or triplet energy transfer, leading to efficient UVCPL emission. The underlying photophysical mechanisms of these two scenarios are clarified by comprehensive optical studies. Intriguingly, UVCPL realized via the triple energy transfer, followed by the triplet–triplet annihilation upconversion processes, demonstrates a 50‐fold enhanced dissymmetry factor glum. Furthermore, stereoselective photopolymerization of diacetylene monomer is demonstrated by using such efficient UVCPL. This study provides both novel insights and a practical approach for realizing UVCPL, which can also be extended to other material systems and spectral regions, such as visible and near‐infrared.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Biomaterials,Biotechnology,General Materials Science,General Chemistry

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