Affiliation:
1. Department of Organic and Nano Engineering Human‐Tech Convergence Program Hanyang University Seoul 04763 Republic of Korea
2. Research Institute of Industrial Science Hanyang University Seoul 04763 Republic of Korea
Abstract
AbstractA Joule heater made of emerging 2D nanosheets, i.e., MXene, has the advantage of low‐voltage operation with stable heat generation owing to its highly conductive and uniformly layered structure. However, the self‐heated MXene sheets easily get oxidized in warm and moist environments, which limits their intrinsic heating efficiencies. Herein, an ultrathin graphene skin is introduced as a surface‐regulative coating on MXene to enhance its oxidative stability and Joule heating efficiency. The skin layer is deposited on MXene using a scalable solution‐phased layer‐by‐layer assembly process without deteriorating the excellent electrical conductivity of the MXene. The graphene skin comprises narrow and hydrophobic channels, which results in ≈70 times higher water impermeability of the hybrid film of graphene and MXene (GMX) than that of the pristine MXene. A complementary electrochemical analysis confirms that the graphene skin facilitates longer‐lasting protection than conventional polymer coatings owing to its tortuous pathways. In addition, the sp2 planar carbon surface with a low heat loss coefficient improves the heating efficiency of the GMX, indicating that this strategy is promising for developing adaptive heating materials with a tractable voltage range and high Joule heating efficiency.
Funder
National Research Foundation
Subject
Biomaterials,Biotechnology,General Materials Science,General Chemistry
Cited by
4 articles.
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