Affiliation:
1. The Wolfson Department of Chemical Engineering Technion ‐ Israel Institute of Technology Haifa 3200003 Israel
2. Department of Chemistry Kansas State University Manhattan KS 66506 USA
3. CO2 Research and Green Technologies Centre Vellore Institute of Technology (VIT) Vellore Tamil Nadu 632014 India
4. The Nancy & Stephen Grand Technion Energy Program (GTEP) Technion – Israel Institute of Technology Haifa 3200003 Israel
Abstract
AbstractThe availability of durable, high‐performance electrocatalysts for the hydrogen oxidation reaction (HOR) is currently a constraint for anion‐exchange membrane fuel cells (AEMFCs). Herein, a rapid microwave‐assisted synthesis method is used to develop a core–shell catalyst support based on a hydrogenated TiO2/carbon for PtRu nanoparticles (NPs). The hydrogenated TiO2 provides a strong metal‐support interaction with the PtRu NPs, which improves the catalyst's oxophilicity and HOR activity compared to commercial PtRu/C and enables greater size control of the catalyst NPs. The as‐synthesized PtRu/TiO2/C‐400 electrocatalyst exhibits respectable performance in an AEMFC operated at 80 °C, yielding the highest current density (up to 3× higher) within the catalytic region (compared at 0.80–0.90 V) and voltage efficiency (68%@ 0.5 A cm−2) values in the compared literature. In addition, the cell demonstrates promising short‐term voltage stability with a minor voltage decay of 1.5 mV h−1. This “first‐of‐its‐kind in alkaline” work may open further research avenues to develop rapid synthesis methods to prepare advanced core–shell metal‐oxide/carbon supports for electrocatalysts for use in the next‐generation of AEMFCs with potential applicability to the broader electrochemical systems research community.
Funder
National Science Foundation
U.S. Department of Energy
Israeli Smart Transportation Research Center
Ministry of Science, Technology and Space
Nancy and Stephen Grand Technion Energy Program
Subject
Biomaterials,Biotechnology,General Materials Science,General Chemistry