Affiliation:
1. School of Nano‐Tech and Nano‐Bionics University of Science and Technology of China Hefei 230026 P. R. China
2. Suzhou Institute of Nano‐tech and Nano‐bionics Chinese Academy of Sciences Suzhou 215123 P. R. China
3. Division of Surgery & Interventional Science University College London London NW3 2PF UK
Abstract
AbstractThe super‐white body might be defined as its reflectivity exceeding 98% at any angle in the visible light spectrum, which can be used in a variety of emerging fields including optics, energy, environment, aerospace, etc. However, elaborate synthesis of a light‐weight, highly reflective super‐white aerogel body remains a great challenge. In this work, fine‐tuning of silica aerogel co‐hydrolyzed precursor ratios, 99.7% reflectivity with angle‐independence in the visible light spectrum has been successfully achieved when the areal density is only 0.129 g cm−2, which breaks through the theoretical bandwidth limit of photonic crystals as well as the measured reflectivity limit of conventional porous materials. Furthermore, the reflectivity of super‐white silica aerogel remains unchanged after various harsh deformations including compression and bending 1000 times, solar (≈800 W m−2), ultraviolet (≈0.68 W m−2), and humidity (100%) aging for 100 days, liquid nitrogen (−196 °C) and high‐temperature (300 °C) thermal shock 100 times. As proofs of performance, the resulting super‐white silica aerogels have been used as the novel standard white plate for better spectrum calibration, as the flexible projector curtains for optical display, as well as the transmitted light reflective layer in the photovoltaic cell for improving the relative power conversion efficiency of 5.6%.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Jiangsu Province
China Postdoctoral Science Foundation
Subject
Biomaterials,Biotechnology,General Materials Science,General Chemistry
Cited by
2 articles.
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