Precise Tuning of Bilayer Ultrasmall MoS2 Featuring Inhibition of Carrier Recombination and Fast Surface Chemistry for Green H2 Evolution

Abstract

AbstractAchieving water splitting to produce green H2, using the noble‐metal‐free MoS2, has attracted huge interest from researchers. However, tuning the number of MoS2 layers precisely while obtaining small lateral sizes to surge the H2‐evolution rate is a tremendous challenge. Here, a bottom‐up strategy is designed for the in situ growth of ultrasmall lateral‐sized MoS2 with tunable layers on CdS nanorods (CN) by controlling the decomposition temperature and concentration of substrate seed (NH4)2MoS4. Here, the bilayer MoS2 and CN coupling (2L–MoS2/CN) exhibits the optimum photocatalytic activity. Compared to thicker MoS2, the 2L–MoS2 has sufficient reduction capacity to drive photocatalytic H2 evolution and the ultrasmall lateral size provides more active sites. Meanwhile, the indirect bandgap, in contrast to the direct bandgap of the monolayer MoS2, suppresses the carrier recombination transferred to 2L–MoS2. Under the synergistic effect of both, 2L–MoS2/CN has fast surface chemical reactions, resulting in the photocatalytic H2‐evolution rate of up to 41.86 mmol g−1 h−1. A novel strategy is provided here for tuning the MoS2 layers to achieve efficient H2 evolution.