Hollow Cu2‐xS@NiFe Layered Double Hydroxide Core–Shell S‐Scheme Heterojunctions with Broad‐Spectrum Response and Enhanced Photothermal‐Photocatalytic Performance

Abstract

AbstractDesigning a reasonable heterojunction is an efficient path to improve the separation of photogenerated charges and enhance photocatalytic activity. In this study, Cu2‐xS@NiFe‐LDH hollow nanoboxes with core–shell structure are successfully prepared. The results show that Cu2‐xS@NiFe‐LDH with broad‐spectrum response has good photothermal and photocatalytic activity, and the photocatalytic activity and stability of the catalyst are enhanced by the establishment of unique hollow structure and core–shell heterojunction structure. Transient PL spectra (TRPL) indicates that constructing Cu2‐xS@NiFe‐LDH heterojunction can prolong carrier lifetime obviously. Cu2‐xS@NiFe‐LDH shows a high photocatalytic hydrogen production efficiency (5176.93 µmol h−1 g−1), and tetracycline degradation efficiency (98.3%), and its hydrogen production rate is ≈10–12 times that of pure Cu2‐xS and NiFe‐LDH. In situ X‐ray photoelectron spectroscopy (XPS) and electron spin resonance (ESR) provide proofs of the S‐scheme electron transfer path. The S‐scheme heterojunction achieves high spatial charge separation and exhibits strong photoredox ability, thus improving the photocatalytic performance.