Affiliation:
1. University of Vigo, Physical Chemistry Department Vigo Spain
2. University of Vigo, Inorganic Chemistry Department Vigo Spain
3. CINTECX University of Vigo, Applied Physic Department Vigo Spain
4. CINTECX University of Vigo, Organic Chemistry Department Vigo Spain
Abstract
AbstractChiroptical responses are valuable for the structural determination of dissymmetric molecules. However, the development of everyday applications based on chiroptical systems is yet to come. We have been earlier using axially chiral allenes for the construction of linear, cyclic, and cage‐shaped molecules that present remarkable chiroptical responses. Additionally, we have developed chiral surfaces through upstanding chiral architectures. Since the goal is to obtain robust chiroptical materials, more recently we have been studying spirobifluorenes (SBFs), a well‐established building block in optoelectronic applications. After theoretical and experimental demonstration, the suitability of chiral SBFs for the development of robust chiroptical systems was certified by the construction all‐carbon double helices, flexible shape‐persistent macrocycles, chiral frameworks for surface functionalization, and structures featuring helical or spiroconjugated molecular orbitals. Here, we give an overview of our contribution to these matters.
Funder
Ministerio de Ciencia e Innovación
Xunta de Galicia
Ministerio de Universidades
Subject
Organic Chemistry,Spectroscopy,Drug Discovery,Pharmacology,Catalysis,Analytical Chemistry
Cited by
1 articles.
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