Affiliation:
1. Department of Chemistry Maharishi Markandeshwar (Deemed to be University) Haryana India
2. Department of Chemistry Himachal Pradesh University Shimla India
3. Department of Chemistry SGRR (PG) College Dehradun India
4. Department of Chemistry H. N. B. Garhwal University Srinagar India
5. Department of Chemistry Faculty of Natural and Agricultural Sciences, North‐West University South Africa
Abstract
AbstractCoS@MorphcdtH NPs and CoS@4‐MPipzcdtH NPs were synthesized by precipitation method involving three mechanisms: inclusion, occlusion, and adsorption. The synthesized NPs were characterized with the help of UV‐Vis spectroscopy, FESEM‐EDAX, powder x‐ray diffraction, TEM, ESIMS, TG/DSC analysis. The morphology of the CoS@MorphcdtH NPs and CoS@4‐MPipzcdtH NPs were hexagonal and rectangular, and the particles were in the range 7–12 nm. UV–visible spectral measurements showed surface plasmon resonance at 320 nm–340 nm with band gap of 3.65 eV–3.86 eV. The catalytically active CoSNPs called were investigated for the reduction of 4‐nitrophenol (4‐NP) via hydrogenation using sodium borohydride (NaBH4) as a reducing agent. Both the CoS NPs successfully reduced 4‐NP to 4‐ aminophenol (4‐AP) in a short time, catalytic performances are almost unchanged for the first five cycles. Herein, we report the preparation and characterizations of efficient active CoS NPs consisting carbodithioic acid framework as a support/capping material, along with catalytic property.