Evaluation of chemical components and quality in Xinhui Chenpi (Citrus reticulata ‘Chachi’) with two different storage times by GC–MS and UPLC

Author:

Shi Junjie123ORCID,Peng Lihua3,Chen Weixuan3ORCID,Qiao Weilin3,Wang Kui12,Xu Yueyang123,Cheng Jinle3

Affiliation:

1. Research Center of Chinese Herbal Resource Science and Engineering, School of Pharmaceutical Sciences Guangzhou University of Chinese Medicine Guangzhou Guangdong China

2. Key Laboratory of Chinese Medicinal Resource from Lingnan (Guangzhou University of Chinese Medicine) Ministry of Education of the People’s Republic of China Guangzhou Guangdong China

3. National Enterprise Technology Center, National and Local Joint Engineering Research Center of Ultrafine Granular Powder of Herbal Medicine Zhongshan Zhongzhi Pharmaceutical Group Co. Ltd. Zhongshan Guangdong China

Abstract

AbstractXinhui Chenpi (XHCP) is a well‐known type of Chenpi (CP) widely used as both a Chinese herb and a food ingredient. While previous studies have explored how the quality of CP changes over time, there has been limited research specifically on XHCP. This study aims to assess the chemical components and quality of XHCP based on total flavonoid content (TF), antioxidant activity (AA), and color value (CV) at two stages: freshly harvested (XHCP‐0Y) and after 3 years of storage (XHCP‐3Y). Thirty‐eight common volatile compounds were identified, and the content of 17 compounds among them, nine nonvolatile compounds, which included one alkaloid (synephrine), three phenolic acids (PA, protocatechuic acid, vanillic acid, and ferulic acid), and five flavonoids (narirutin, hesperidin, sinensetin, nobiletin, and tangeretin), were firstly detected by the newly developed gas chromatograph–mass spectrometer (GC–MS) and ultra‐performance liquid chromatography (UPLC) methods. Compared to XHCP‐0Y, the content of 17 volatile compounds and synephrine decreased in XHCP‐3Y to varying degrees, while the content of PA, five flavonoids, TF, AA, and CV increased. The reduction of dryness caused by volatile compounds and the enhancement of efficacy related to PA, flavonoids, and AA suggested improved quality of XHCP after 3 years of storage. The methods developed in this study show promise for evaluating the quality of XHCP during the aging process.

Publisher

Wiley

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