Synthesis and crystal growth of novel layered bismuthides ATM2Bi2 (A=K, Rb, Cs; TM=Zn, Cd), electron‐deficient compounds with the ThCr2Si2 structure-Reference-Cited by-同舟云学术

Synthesis and crystal growth of novel layered bismuthides ATM₂Bi₂ (A=K, Rb, Cs; TM=Zn, Cd), electron‐deficient compounds with the ThCr₂Si₂ structure

Published:2023-01-31 Issue:6-7 Volume:649 Page:
ISSN:0044-2313
Container-title:Zeitschrift für anorganische und allgemeine Chemie
language:en
Short-container-title:Zeitschrift anorg allge chemie

Author:

Shilov Andrey I.¹²,Pervakov Kirill S.²,Lyssenko Konstantin A.¹³,Vlasenko Vladimir A.²,Efremov Dmitri V.⁴^ORCID,Aswartham Saicharan⁴^ORCID,Simonov Sergey V.⁵,Morozov Igor V.¹,Shevelkov Andrei V.¹^ORCID

Affiliation:

1. Department of Chemistry Lomonosov Moscow State University 119991 Moscow Russia

2. P. N. Lebedev Physical Institute Russian Academy of Sciences 119991 Moscow Russia

3. National Research University Higher School of Economics Myasnitskaya str., 20 101000 Moscow Russia

4. Leibniz Institute for Solid State and Materials Research IFW Dresden 01069 Dresden Germany

5. Institute of Solid-State Physics Russian Academy of Sciences 142432 Chernogolovka Moscow oblast Russia

Abstract

AbstractWe report crystal growth and characterization of 4 new ternary layered bismuthides with compositions KZn2Bi2 (I), RbZn2Bi2 (II), RbCd2Bi2 (III), and CsCd2Bi2 (IV) that belong to the vast 122 family of compounds. Single crystals were grown by self‐flux technique and characterized by a combination of powder X‐ray diffraction, scanning electron microscopy, energy‐dispersive X‐ray spectroscopy, and single crystal X‐ray diffraction. All new compounds crystallize in the layered ThCr2Si2 structure type and exhibit the plate‐like morphology with weak bonding between layers. A significant structural difference between ACd2Bi2 and AZn2Bi2 is found and discussed.

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.202200298

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