Cationic Mononuclear Bi(rhenacyclopropene) Complexes from Reactions of ReCl3(PMePh2)3 with RC≡CH (R=alkyl)-Reference-Cited by-同舟云学术

Cationic Mononuclear Bi(rhenacyclopropene) Complexes from Reactions of ReCl₃(PMePh₂)₃ with RC≡CH (R=alkyl)

Published:2023-06-09 Issue:13 Volume:649 Page:
ISSN:0044-2313
Container-title:Zeitschrift für anorganische und allgemeine Chemie
language:en
Short-container-title:Zeitschrift anorg allge chemie

Author:

Li Lei¹,Zhao Yue¹,Zhou Yan²,Bai Wei¹^ORCID

Affiliation:

1. School of Chemistry Dalian University of Technology Liaoning 116024 P.R. China

2. School of Chemistry and Chemical Engineering Guangxi University for Nationalities Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Key Laboratory of Guangxi Colleges and Universities for Food Safety and Pharmaceutical Analytical Chemistry Nanning 530008 P.R. China

Abstract

AbstractReactions of terminal alkynes (alkyl−C≡CH) and internal alkynes with rhenium(III) phosphine complex ReCl3(PMePh2)3 were studied, producing cationic mononuclear bi(rhenacyclopropene) complexes and η2‐alkyne complexes, respectively. The bi(rhenacyclopropene) complexes represent rare examples of well‐defined mononuclear metal complexes containing two η2‐vinyl ligands, as well as bis(dialkylcarbene) complexes of transition metals.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.202300114

Reference62 articles.

1. Recent reviews see:

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