Crystal structure and properties of the magnetically frustrated B‐site ordered Sr<sub>2</sub>CaOsO<sub>6</sub> double perovskite-Reference-Cited by-同舟云学术

Crystal structure and properties of the magnetically frustrated B‐site ordered Sr₂CaOsO₆ double perovskite

Published:2023-08-09 Issue:18 Volume:649 Page:
ISSN:0044-2313
Container-title:Zeitschrift für anorganische und allgemeine Chemie
language:en
Short-container-title:Zeitschrift anorg allge chemie

Author:

Thakur Gohil S.¹²³^ORCID,Schnelle Walter³,Jansen Martin⁴^ORCID

Affiliation:

1. Faculty of Chemistry and Food Chemistry Technical University 01069 Dresden Germany

2. Würzburg–Dresden Cluster of Excellence‘ct.qmat',Technical University 01069 Dresden Germany

3. Max Planck Institute for Chemical Physics of Solids Nöthnitzer Str. 40 01187 Dresden Germany

4. Max Planck Institute for Solid State Research Heisenbergstraße 1 70569 Stuttgart Germany

Abstract

AbstractThe B‐site ordered double perovskite Sr2CaOsO6 has been synthesized by a solid‐state reaction under ambient pressure. Sr2CaOsO6 is isostructural to Sr2NaOsO6 and Sr2CaReO6, thus crystallizes in the monoclinic space group P21/n, in contrast to cubic lattice symmetry reported in an earlier publication. The compound remains paramagnetic down to a temperature of 2 K. This finding is of relevance with regard to the high‐temperature ferromagnetism observed in Sr3OsO6 thin films and may find interest in view of possible exotic ground states in frustrated magnetic systems.

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.202300061

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