Atmospheric Water Harvesting in Microporous Organic Polymers Constructed from Trazine and Benzimidazole Units

Author:

Huang Jitao12,Yang Yisi1,Chen Liangji1,Zhang Zhangjing1ORCID,Xiang Shengchang1ORCID

Affiliation:

1. FuJian Provincial Key Laboratory of Polymer Materials College of Chemistry and Materials Science Fujian Normal University 32 Shangsan Road Fuzhou 35007 PR China

2. College of Chemistry and Materials Science Ningde Normal University 1 xueyuan Road Ningde 352100 PR China

Abstract

AbstractPorous materials‐assisted atmospheric water harvesting (AWH) approaches are attractive for addressing the severe shortage of freshwater resources. Herein, ionothermal polymerization approach was employed to realize four porous organic polymers (FJU‐CTFs) with strong hydration stability and low skeleton density for atmospheric water harvesting. The materials exhibited ultra‐high water vapor adsorption capacity (1108 cm3 g−1), s‐type adsorption isotherms, and rapid filling of water vapor in the pores of the materials under low humidity conditions. It has the characteristics of atmospheric water harvesting from the air at lower humidity (30 %–40 %) and narrow temperature (30–35 °C). A total of 30 times of water adsorption‐desorption cycles showed the excellent working ability and hydrolytic stability of FJU‐CTFs, which provided new solutions for the application of porous materials in AWH and expanded new material types.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Inorganic Chemistry

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