Affiliation:
1. College of Material Science and Engineering Changchun University of Technology Changchun China
2. Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences Changchun Institute of Applied Chemistry Changchun China
3. Jilin COFCO Biochemical Technology Co., Ltd. Changchun China
Abstract
AbstractBioplastic films with excellent barrier properties were successfully prepared from poly(butylene adipate‐co‐terephthalate) (PBAT), thermoplastic starch (TPS), and poly((R)‐3‐hydroxybutyrate‐co‐(R)‐3‐hydroxyhexanoate) (PHBHHx). The rheological, mechanical, barrier, dynamic mechanical properties, and microstructure of the PBAT/TPS/PHBHHx films were studied. The transition of the continuous phase in the blend significantly affects the properties of the films. The increase in PHBHHx content results in its transition from a dispersed phase to a continuous phase. This phase transition, along with the consequent increase in the crystallinity of PHBHHx, greatly enhances the barrier properties of the film. The percentage crystalline degree of PHBHHx increased from 10.9% to 25.1% with increasing PHBHHx content from 0% to 50%. The film containing 50% PHBHHx showed a significant decrease in both water vapor permeability (WVP) and oxygen permeability (OP) by 75.1% and 69.6%, respectively. It found that the film containing 50% PHBHHx exhibited a decrease of elongation at break from 505% to less than 10% but an unusual increase of tensile strength after a 72‐hour aging test, which is different from PBAT and PBAT/TPS films. However, this indicates that the extensibility of PHBHHx is more susceptible to the effects of aging test, leading to the rearrangement of polymer chains from disordered to ordered morphology.