Effect of Mechanical Properties on the Miscibility of a PHBV/PP Blend

Author:

Hamour Noura1ORCID,Boukerrou Amar1,Beaugrand Johnny23

Affiliation:

1. Laboratoire des Matériaux Polymères Avancés (LMPA) Faculté de Technologie Université de Bejaia Bejaia 06000 Algeria

2. INRA, URCA, UMR614 Fractionnement des AgroRessources et Environnement Reims 51100 France

3. INRA, UR1268 Biopolymères Interactions Assemblages Nantes 44300 France

Abstract

AbstractThe present work is dedicated to the study of the mechanical and rheological properties of poly (hydroxybutyrate‐co‐hydroxyvalerate) PHBV blends with polypropylene PP. Given the incompatibility of these homopolymers, the use of a compatibilizing agent is essential. For this purpose, titanium dioxide (TiO2) and maleic anhydride (MA) are used. These constituents are chosen on the basis of some work that showed a high compatibility between it and the two homopolymers PHBV and PP. Thus, this copolymer has a great potential to improve the interfacial adhesion between these two polymers. From the results obtained from the techniques used in this study, it can be concluded that the immiscible PP/PHBV mixture can be effectively compatibilizing for by maleic anhydride. The latter is able to create chemical bonds between the macromolecular chains of the two polymers at the interface and therefore improves their properties.

Publisher

Wiley

Subject

Materials Chemistry,Polymers and Plastics,Organic Chemistry,Condensed Matter Physics

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