Affiliation:
1. School of Science Chongqing University of Posts and Telecommunications Nan'an District Chongqing 400065 China
2. Department of Physics P.C. Jabin Science College Hubballi Karnataka 580031 India
3. School of Electronic and Information Engineering Chongqing Three Gorges University Wanzhou Chongqing 404000 China
4. School of Science Lanzhou University of Technology Lanzhou 730050 China
5. Department of Chemistry College of Science King Saud University P.O. Box 2455 Riyadh 11451 Saudi Arabia
6. Department of Materials Science and Engineering and Chemical Engineering Universidad Carlos III de Madrid Avenida de la Universidad 30 Leganés Madrid 28911 Spain
7. Division of Research and Development Lovely Professional University Phagwara Punjab 144411 India
Abstract
AbstractA simple solution combustion method is used to synthesize spinel type MgFe2O4 (MFO) and CoCr2O4 (CCO) oxides, which are combined with the mechanical mixing method to construct a Z‐scheme MFO/wt%CCO heterojunction, which effectively degraded tetracycline hydrochloride (TC) under simulated sunlight irradiation. Various characterization techniques are used to confirm the phase structure, composition, near‐spherical morphology, ferromagnetic behavior, optical properties, and photocatalytic activity of Z‐scheme MFO/wt%CCO heterojunction. A variety of environmental experimental parameters confirmed that when the optimal initial TC concentration is 50 mg L−1, the catalyst content is 1 g L−1, and pH 13, the degradation percentage of TC by the MFO/75%CCO composites reached 89%. Active species verification experiments showed that the hole (h+), hydroxyl radical (•OH), and superoxide radical (•O2
−) are the main active species in photocatalytic reactions. Based on mass spectrometry, toxicity analysis, and energy band theory, the degradation pathway, toxicity, and photocatalytic mechanism of MFO/75%CCO composites for the degradation of TC are discussed in detail.
Subject
General Environmental Science,Renewable Energy, Sustainability and the Environment