Characterization of Regolith And Trace Economic Resources (CRATER): An Orbitrap‐based laser desorption mass spectrometry instrument for in situ exploration of the Moon

Author:

Ray Soumya1ORCID,Arévalo Ricardo1ORCID,Southard Adrian2,Willhite Lori1ORCID,Bardyn Anais1,Ni Ziqin1ORCID,Danell Ryan3ORCID,Grubisic Andrej4,Gundersen Cynthia5,Llano Julie5,Yu Anthony4,Fahey Molly4,Hernandez Emanuel4,Graham Jacob4,Lee Jane4,Ersahin Akif6,Briois Christelle7ORCID,Thirkell Laurent7,Colin Fabrice7,Makarov Alexander8

Affiliation:

1. University of Maryland College Park Maryland USA

2. CRESST II College Park Maryland USA

3. Danell Consulting Winterville North Carolina USA

4. NASA Goddard Space Flight Center Greenbelt Maryland USA

5. AMU Engineering Miami Florida USA

6. MAE Aerospace South Glastonbury Connecticut USA

7. Laboratoire de Physique et Chimie de l'Environnement et de l'Espace Orléans France

8. Thermo Fisher Scientific Bremen Germany

Abstract

RationaleCharacterization of Regolith And Trace Economic Resources (CRATER), an Orbitrap™‐based laser desorption mass spectrometry instrument designed to conduct high‐precision, spatially resolved analyses of planetary materials, is capable of answering outstanding science questions about the Moon's formation and the subsequent processes that have modified its (sub)surface.MethodsHere, we describe the baseline design of the CRATER flight model, which requires <20 000 cm3 volume, <10 kg mass, and <60 W peak power. The analytical capabilities and performance metrics of a prototype that meets the full functionality of the flight model are demonstrated.ResultsThe instrument comprises a high‐power, solid‐state, pulsed ultraviolet (213 nm) laser source to ablate the surface of the lunar sample, a custom ion optical interface to accelerate and collimate the ions produced at the ablation site, and an Orbitrap mass analyzer capable of discriminating competing isobars via ultrahigh mass resolution and high mass accuracy. The CRATER instrument can measure elemental and isotopic abundances and characterize the organic content of lunar surface samples, as well as identify economically valuable resources for future exploration.ConclusionAn engineering test unit of the flight model is currently in development to serve as a pathfinder for near‐term mission opportunities.

Funder

National Aeronautics and Space Administration

Publisher

Wiley

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