Synthesis and post‐polymerization modification of poly(diglycidyl fumarate)s and their thermal properties

Author:

Mori Yasuyuki12,Tada Ryu2,Okano Ippei3,Tamaso Ken‐ichi3,Ogawa Ryo3,Shinozuka Toyofumi3,Furusho Yoshio12,Endo Takeshi2ORCID

Affiliation:

1. Division of Chemistry, Department of Fundamental Biosciences Shiga University of Medical Science Otsu Japan

2. Molecular Engineering Institute Shiga University of Medical Science Otsu Japan

3. Functional Polymers Development Laboratory R&D Division Saitama Japan

Abstract

AbstractThe radical polymerization of diglycidyl fumarates was performed to give the poly(fumarate)s bearing epoxy groups in the side chains. Their post‐polymerization modification with carbon dioxide afforded the poly(fumarate)s containing the five‐membered cyclic carbonate structures by the reaction of epoxy groups in the polymer side chains with carbon dioxide. Besides, the thermal stability and behavior of the obtained poly(fumarate)s were examined by thermogravimetric and differential scanning calorimetry analyses.

Publisher

Wiley

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