Synthesis and properties of highly thermally stable ultrathin films of fluorine‐containing hyperbranched polybenzoxazoles

Author:

Maekawa Hiroyuki1,Nakamura Kosyu1,Kudo Hiroto1ORCID

Affiliation:

1. Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering Kansai University Suita‐shi Osaka Japan

Abstract

AbstractIn this paper, we aimed to develop ultrathin films of hyperbranched polybenzoxazole with a thickness in the range between 1 and 100 nm. They are expected to have great potential for various applications as functional materials due to their high thermal stability, good chemical resistance and mechanical strength. The synthesis of various hyperbranched poly(o‐hydroxyamide)s as precursors of polybenzoxazole was examined by the polycondensation of 2,2‐bis(3‐amino‐4‐hydroxyphenyl)propane (AHP) and 2,2‐bis(3‐amino‐4‐hydroxyphenyl)hexafluoropropane (AHFP) with 1,3,5‐benzenetricarbonyl trichloride (BCC), yielding the corresponding hyperbranched poly(o‐hydroxyamide), poly(AHFPmco‐AHPnco‐BCC2.0), with Mn in the range between 12,870 and 22,210 in satisfactory yields. Poly(AHFP3.0co‐BCC2.0), poly(AHFP2.25co‐AHP0.75co‐BCC2.0), and poly(AHFP1.50co‐AHP1.50co‐BCC2.0) showed good solubility and film‐forming ability, and ultrathin films 8.9–88.6 nm thick were prepared on silicon wafers. Heating of the ultrathin films of poly(AHFPmco‐AHPnco‐BCC2.0) on a hot plate at 350 °C for 1 h afforded the corresponding ultrathin films of hyperbranched polybenzoxazole, poly(AHFPmcyclo‐AHPncyclo‐BCC2.0), with a thickness of 5.3–82.4 nm. Double‐layer thin films consisting of resist materials on top of hyperbranched polybenzoxazole were also prepared.

Publisher

Wiley

Subject

Materials Chemistry,Polymers and Plastics,Physical and Theoretical Chemistry

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