Synthesis of Silylene and Silyl(silylene)metal Complexes

Author:

Ogino Hiroshi

Publisher

Wiley

Subject

Materials Chemistry,General Chemical Engineering,Biochemistry,General Chemistry

Reference60 articles.

1. Abbreviations used in this paper: Cp = C5H5; Cp* = C5Me5; Cp? = general expression for substituted and nonsubstituted cyclopentadienyl ligands; HMPA = hexamethylphosphoramide; OTf = trifluoromethanesulfonate ion; Mes = mesityl; pTol = p-tolyl; TPP = meso-tetra-p-tolylporphyrin.

2. (a) In The Chemistry of Organic Silicon Compounds; ; Eds.; Wiley: New York, 1989; p 1415. (b) In The Silicon-Heteroatom Bond; ; Eds; Wiley: New York, 1991; p 245, 309.

3. Disproportionation of pentamethyldisilane and sym-tetramethyldisilane catalysed by platinum complexes

4. Recently we examined similar systems: for instance, heating Si2Me5H in the presence of a catalytic amount of cis-PtMe2(PEt3)2 at 90 °C for 18 h in C6D6 afforded linear oligosilanes up to Si9Me19H.5

5. ; ; Unpublished results.

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