Abatement of volatile organic compounds employing a thermoplastic nano‐photocatalyst layered on a glass reactor

Author:

Vento Fabiana1ORCID,Nicosia Angelo12ORCID,Fiorenza Roberto13ORCID,Scirè Salvatore13ORCID,Pellegrino Anna Lucia1ORCID,Mezzina Lidia1ORCID,Raciti Giulia14ORCID,Mineo Placido1256ORCID

Affiliation:

1. Department of Chemical Sciences University of Catania V.le A. Doria 6 95125 Catania Italy

2. I.N.S.T.M. UdR of Catania University of Catania V.le A. Doria 6 95125 Catania Italy

3. C.I.R.C.C. (Interuniversity Consortium in Chemical Reactivity and Catalysis) UdR of Catania University of Catania V.le A. Doria 6 95125 Catania Italy

4. Faculty of Engineering Østfold University College P.O. Box 700 1757 Halden Norway

5. Institute of Polymers Composites and Biomaterials National Research Council (IPCB-CNR) Via P. Gaifami 18 95126 Catania Italy

6. Institute for Chemical and Physical Processes CNR-IPCF V.le F. Stagno d'Alcontres 37 98158 Messina Italy

Abstract

AbstractIndustrial development and urbanization have increased the emission of Volatile Organic Compounds (VOCs) into the atmosphere, causing environmental and health risks. Several approaches are used for their abatement, including chemical, thermo‐ and photo‐catalytic oxidations, but they are not fully satisfactory. In this work, a thermoplastic TiO2‐based photo‐catalyst was used as a coating layer of a glass‐reactor. Solar‐triggered photocatalytic degradation of ethanol, toluene, and acetone (used as model VOCs) highlights the better performance of the coated photoreactor than that of TiO2 nanopowder. The influence of the pollutant flow rate on the photodegradation performance of the system was also investigated, revealing an inverse relationship between degradation and flow rates. The experimental data suggest that our approach provides a cost‐effective and efficient way to boost the abatement of VOCs, useful for further industrial‐scale applications. The morphology and the compositional homogeneity of the nanocomposite coating were addressed through Field Emission Scanning Electron Microscopy coupled with Energy Dispersive X‐ray Analysis.

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Analytical Chemistry

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