Affiliation:
1. School of Materials Science and engineering Key Laboratory of Photovoltaic Materials of Henan Province Henan Normal University Xinxiang 453007 China
2. School of Physics Henan Normal University Xinxiang 453007 China
Abstract
AbstractNowadays, amine containing electrode interface material destroy the non‐fullerene acceptor becomes a hard nut to crack for organic solar cells. Developing water‐soluble interface material which is no chemical reaction with non‐fullerene acceptor is an important research theme. Here, we report two bi‐triangular pyramidal electronic configuration organic‐phosphonium bromides as non‐amine cathode interfacial layer for fabricating high‐efficiency stable organic solar cells. The power conversion efficiency (PCE) of inverted device structure with PBDB‐T/ITIC as active layer is up to 11.58 % which is great larger than control device PCE (9.35 %). Same device structure with PM6/Y6 as active layer, the PCE is up to 15.26 % and also is dramatically higher than the referred device PCE 14.36 %. Meanwhile, the devices show greatly improved stability by organic‐phosphonium bromide interlayer.