Microwave‐Assisted Silver‐Catalyzed Synthesis of Biaryl Compounds

Author:

Bharodiya Akshay1,Desai Bhargav1,Patil Rachit S.2,Bhukya Hussain2,Sivaiah Areti1,Naveen Togati1ORCID

Affiliation:

1. Department of Chemistry Sardar Vallabhbhai National Institute of Technology Surat Gujarat 395 007 India

2. Department of Biology Indian Institute of Science Education and Research Tirupati Andhra Pradesh – 517 507 India

Abstract

AbstractA rapid, ligand/oxidant/base‐free, silver carbonate‐catalyzed homocoupling reaction of aryl boronic acids under microwave irradiation for the synthesis of symmetric biaryls is described here. This protocol tolerates a wide range of electron‐donating, electron‐withdrawing, and heterocyclic boronic acids to provide the corresponding biaryl products in good to excellent yields. The features of this strategy include a wide substrate scope, mild reaction conditions, high functional group tolerance, good to excellent yields, and short reaction time.

Publisher

Wiley

Subject

General Chemistry

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