Cobalt Ferrite Incorporated Ocimum sanctum Nanocomposite Matrix as an Interface for Adsorption of Organic Dyes: A Sustainable Alternative

Author:

Sharma Atul1,Rasheed Shoaib1,Mangla Divyanshi2,Choudhry Arshi1,Shukla Sneha1,Chaudhry Saif Ali1ORCID

Affiliation:

1. Environmental Chemistry Research Laboratory Department of Chemistry, Jamia Millia Islamia New Delhi 110025 India

2. Bio/Polymer Laboratory Department of Chemistry, Jamia Millia Islamia New Delhi 110025 India

Abstract

AbstractThe preparation of Cobalt ferrite‐Ocimum sanctum nanocomposite, referred to as CoFe2O4/OS, has been reported along with its application for the treatment of water containing hazardous organic contaminants. A simple co‐precipitation approach was applied for synthesis of magnetic nanocomposite, and a thorough analysis for its characterization was conducted using several spectroscopic and microscopic techniques. The characterization results showed that the magnetic nanocomposite exhibited substantial functional groups of Ocimum sanctum powder and magnetic ferrite part. The adsorption investigation of nanocomposite for removal of two cationic dyes was carried out with varying parameters, such as pH, contact time, temperature, concentration, and composite dosage. The sorption process was proved feasible and exothermic at the tested temperatures (303–323 K). The sorption data followed Freundlich and Temkin isotherms which recommended the physisorption progression. The kinetic study revealed a pseudo‐second order rate of sorption process for both dye molecules. The facile preparation, economical cost, significant magnetic character, and high sorption capacity will surely construct the water treatment system more competent with the use of CoFe2O4/OS.

Publisher

Wiley

Subject

General Chemistry

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